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OXIDIZING AGENT

In chemistry, an oxidizing agent (oxidant, oxidizer) is a substance that has the ability to oxidize other substances — in other words, to cause them to lose electrons. Common oxidizing agents are oxygen, hydrogen peroxide and the halogens.

 

In one sense, an oxidizing agent is a chemical species that undergoes a chemical reaction that removes one or more electrons from another atom. In that sense, it is one component in an oxidation-reduction (redox) reaction. In the second sense, an oxidizing agent is a chemical species that transfers electronegative atoms, usually oxygen, to a substrate. Combustion, many explosives, and organic redox reactions involve atom-transfer reactions.

 

Common oxidizing agents (O-atom transfer agents)

Oxygen (O2)

Ozone (O3)

Hydrogen peroxide (H2O2) and other inorganic peroxides, Fenton's reagent

Fluorine (F2), chlorine (Cl2), and other halogens

Nitric acid (HNO3) and nitrate compounds

Sulfuric acid (H2SO4)

Peroxydisulfuric acid (H2S2O8)

Peroxymonosulfuric acid (H2SO5)

Chlorite, chlorate, perchlorate, and other analogous halogen compounds

Hypochlorite and other hypohalite compounds, including household bleach (NaClO)

Hexavalent chromium compounds such as chromic and dichromic acids and chromium trioxide, pyridinium chlorochromate (PCC), and chromate/dichromate compounds

Permanganate compounds such as potassium permanganate

Sodium perborate

Nitrous oxide (N2O), Nitrogen dioxide/Dinitrogen tetroxide (NO2 / N2O4)

Potassium nitrate (KNO3), the oxidizer in black powder

Sodium bismuthate

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